Here is something of which I wish I was aware prior to the change over from network to named-user licenses. If all of your users were already set up with BIM 360 Design licenses (which were always named-user) and were always signed into Revit with their Autodesk Account, then this will not be an issue for you. But if you have users that are not signed into Autodesk Account when using Revit under a network license, chances are that their default Revit user names are not the same as the Username on their Autodesk Accounts. Make certain everyone synchronizes and relinquishes all object ownership in all Revit models while still using a network license BEFORE you change them to named user.
Once on named user, your users have to be signed in, and their Revit user names will be "locked" as the Usernames associated with their Autodesk Account. If that differs from their previous user names, they will not be able to synchronize their old local files, nor will they be able to create a new local under their old user names so that they can relinquish ownership of objects.
The users may be able to copy/paste unsynchronized changes, and the central file can be opened detached and then a new central file can be created from the detached copy to get rid of ownership issues (once everyone who can synchronize/relinquish does so), but nobody really wants to do any of that.
You might think no one would ever close Revit having only saved changes locally, or without relinquishing all ownership, but you would be wrong. I have already run into this twice.